Deep Cryogenic Tempering - 
One of Metalworking's Best Kept Secrets

An abstract of a presentation given at the DIS Ft. Worth meeting

by:  John Koucky, 300 Below, Inc.

What is Deep Cryogenic Tempering?

It is -

  1. Freezing the material at -300oF to modify the microstructure and improve the properties.

  2. A "dry" process.

  3. A "one time" treatment.

  4. A "through" treatment.

  5. A treatment to improve properties - particularly the wear properties.

What are the benefits of Deep Cryogenic Tempering?

Deep Cryogenic Treatment at -300oF can make a major contribution to solving these problems:

  1. HIGH ABRASIVE WEAR in cutting tools, molds, dies, bearings, etc.

  2. HIGH CORROSIVE WEAR in chemical, food and oil equipment applications.

  3. HIGH EROSIVE WEAR from wind, water and other abrasive grit carriers.

  4. DISTORTIONS induced by design, forming, machining or environment.

  5. STRESS RELIEF in complex tools, components and welds.

  6. STRESS RELIEF CRACKING in weld zones in corrosive atmospheres.

  7. SURFACE FINISH in any applications where long life is needed.

  8. STABILIZATION in parts and components as a result of stresses.

  9. MACHINABILITY in aluminum and copper parts.

  10. ELECTRODE LIFE in copper resistance welding electrodes.

What happens during Deep Cryogenic Tempering? (Ferrous components)

  1. Most of the retained austenite is transformed into martensite. The martensite is then tempered to change it into tempered martensite.

  2. Small complex carbides called eta carbides are precipitated out.

  3. Residual stresses are greatly reduced.

Alloys with greater than 0.40% carbon REQUIRE Cryogenic Tempering to finish martensite transformation.

Deep Cryogenic Tempering is performed in batch type Cryo Processors using primarily liquid nitrogen. The tempering process is fully automated with computer controls to offer maximum benefits.

What materials are favorably affected by Deep Cryogenic Tempering?

Ferrous Materials:

1. Tool steels
2. Higher carbon, higher alloy materials
3. Martensitic stainless steels
4. Gray cast iron

Aluminum

Brass

Tungsten carbide

Other applications of the process are

1. Musical instruments
2. Motor sport applications
3. Gun barrels
4. Sporting goods
5. Disc brake rotors
6. Others such as composites, etc.

Deep Cryogenic Tempering at -300oF vastly improves the wear properties compared to 'cold treatment' at  -100oF. (See table 1.)

TABLE 1. Test Results (% Wear Increase after Cryogenic Tempering)

Type of Steel % Improvement

AISI #

Description (-110oF)  (-310oF)

D-2

High carbon/chromium die

316

817

A-2

Chromium cold work die

204

560

S-7

Silicon tool steel

241

503

52100

Bearing steel

195

420

0-1

Oil hardening cold work die

221

418

A-10

Graphite tool steel

230

264

M-1

Molybdenum high speed

145

225

H-13

Chromium/moly hot die

164

209

M-2

Tungsten/moly high speed

117

203

T-1

Tungsten high speed

141

176

CPM-10V

Alloy steel

94

131

P-20

Mold steel

123

130

440

Martensitic stainless

128

121

430

Ferritic stainless

116

119

303

Austenitic stainless

105

110

8620

Nickel-chromium-moly steel

112

104

C1020

Carbon steel

97

98

AQS

Graphitic cast iron

96

97

A-6

Manganese, air, cold work die

73

97

T-2

Tungsten high speed steel

72

92

Field test results with Deep Cryogenic Tempering. (See table 2.)

Our expert computer-controlled patented systems which enable 
CONSISTENCY AND MAXIMIZED GAIN in the following areas:

Reduced:  Abrasive Wear, Corrosive Wear, Erosive Wear, Distortion

Increased:  Stress Relief, Stabilization, Machinability

Significantly Increased:  Useful Life

Table 2
Tool Type Company Tool Material % Improvement
Drills Aircraft Manufacturer M42, M7, C2 300
Milling Aircraft Manufacturer M7 250
Deburring University Study Inconel 400
Gear Cutter Major Manufacturer Ti-N Coated 350
Broach Metal Milling Co. Carbide 300
Punching Major Manufacturer M7 600
End Mill Aerospace Mfg. M42 450
Hob Turbine Mfg. M2-M7 300
Face Mill Aerospace C2 Carbide 400
Key Cutter Aircraft Mfg. M2-M7 250
Slicer Plastics Mfg. M7 600
Chipper Box Mfg. Carbide 500
Shredder Paper Mfg. M7 400
Tap Tool Maker C2 Carbide 600
Die Casting Company Hi Ni Alloy 300
Dentistry Dentist 400 Stainless 500
Broach Auto Mfg. Hi Nickel 250
Logging Logging Company Saw Chain 400
Milling Machine Shop 347 Stainless 375
Woodcutting Pro Woodworker HSS 500
Stamping Die Steel Furniture D2 1000
Corrosion University Study S2, M2, 4142, 316 Red. All Corrosion
Machinability Machine Shop Thin Wall Alum. 50% Time Savings
Electrode 7 Studies Welding 600% Average

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