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MOLTEN METAL FILTRATION |
In all cases, the studies used filters that are generally
recommended for use with ductile iron. All the foam
filters tested are 10 ppi (pores per inch). The extruded
filters are 100 csi (cells per square inch). The pressed
filters have a cell diameter of 0.100 inches (2.5 mm).
3FILTRATION EFFICIENCY
The ability of a filter to remove inclusions is obviously
an important parameter. Ceramic tile filters are
generally more efficient at removing micro inclusions
than traditional methods such as extensive running
systems and whirl gates. The removal of such inclusions
will have a positive effect on the machinabilty of
castings, (1), resulting in extended tool life. The
fatigue strength will also be improved as a result of
improved as cast surface finish.
3.1FILTRATION MECHANISMS
Filters remove inclusions using a variety of mechanisms
(2). Some may be more efficient at one mechanism than
others. The following is a brief description of each of
the mechanisms, using cellular filters as an example.
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Figure 1. |
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Figure 2. A large sand agglomerate retained by screening. |
3.1.1SCREENING
Filters will collect dross particles and inclusions that
are larger than the filter hole or pore size on their
upstream face. These particles are unable to pass through
to the casting cavity due to their physical size. Figure 1 shows a diagram
describing the screening mechanism. Figure 2 shows a
large sand agglomerate retained on the filter surface by
screening.
3.1.2CAKE FILTRATION
The larger dross particles collected on the upstream face
during the screening phase will form what is known as a
"filter cake". This cake will itself act as an
efficient filtration media. This phase is able to collect
particles smaller than the cells of the filter. Figure 3 shows a diagram
showing the mechanism of cake filtration.
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Figure 3. |
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Figure 4. A
micro-inclusion bridge |
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Figure 5. Deep bed filtration. |
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Figure 6. A sand
particle retained |
In ductile iron, a more probable mechanism for the
removal of micro-inclusions, (<1% of the cell size), is through the formation of "inclusion bridges". small eddy currents, formed when the metal stream splits on the active face of the filter, are generated. these eddy currents will encourage small non metallic particles to make contact with the edges of the cell. as the pour progresses these particles will continue to adhere to each other and will eventually form an "inclusion bridge". fig 4 shows an inclusion bridge formed from minute sulfide and oxide particles in ductile iron. the phenomenon is regularly observed in both cellular and foam type filters.
<1% of the cell size), is
through the formation of "inclusion
bridges." Small eddy currents, formed when the
metal stream splits on the active face of the filter, are
generated. These eddy currents will encourage small
non-metallic particles to make contact with the edges of
the cell. As the pour progresses these particles
will continue to adhere to each other and will eventually
form an "inclusion bridge." Figure 4
shows an inclusion bridge formed from minute sulfide and
oxide particles in ductile iron. The phenomenon is
regularly observed in both cellular and foam type
filters.
3.1.3DEEP BED
FILTRATION
The internal structure of the filter is able to capture
small particles of dross and slag. Small variations in
flow will cause particles to touch the ceramic walls of
the filter. Once contact is made, the inclusions will
have a tendency to adhere to the ceramic material. Figure 5 shows a diagram
of the mechanism. Figure 6 shows a sand grain retained by
deep bed filtration in a pressed cellular filter.
3.2RELATIVE FILTRATION EFFICIENCY
Many studies have been undertaken in an attempt to
quantify and compare the filtration efficiency of
filters. Such a study (3) was implemented to compare the
three filter types under discussion. The study was also
used to examine the effectiveness of filtration in
general. Filtered and unfiltered castings were poured for
the study. Quantitative and qualitative examinations were
then performed.
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Figure 7. The step block casting designed for the filtration efficiency study. |
For the tests to be valid
it was necessary to keep parameters such as composition
of the melt, pouring temperature and pouring time as
consistent as possible. The melt composition can be kept
constant by pouring each casting from the same melt.
This, however, will inevitably lead to temperature losses
between the first and last pours. To account for this
variability, four series of castings were poured and the
order of pouring was reversed between the first two heats
and the last two. Each series started and ended with an
unfiltered casting The system choke was at the base of
the sprue. This was done to ensure that pouring time did
not vary with filter type.
A step block casing was designed for the study. A diagram
of the complete system can be seen in Figure 7. The casting had
a 3 inch, (75 mm), thick section and a 1/4 inch, (75 mm),
thick section. The system was gated so that the iron
flowed through a drag runner, up through the filter, and
into a cope runner.
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Figure 8. A cope surface with a rating of 3 - good. |
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Figure 9. A cope surface with a rating of 2 - fair. |
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Figure 10. A cope surface with a rating of 1 - bad. |
3.2.1QUALITATIVE
METALLOGRAPHY
The cope surface of each of the castings was examined
visually for pit type defects. These defects are normally
associated with macroscopic silicate inclusions. The
castings were rated as "3" for a good surface
finish, "2" for a fair surface finish, and
"1" for a bad surface finish. Examples as to
what was regarded as good, fair and bad can be seen in
figures 8, 9 and 10.
All of the castings poured were scored using the above
system. The average scores of each filter type can be
seen in the graph in figure
11.
As can be seen from the average ratings, the choice of
filter does not seem to make any difference to the
surface quality of the castings. All the filters tested
produced good quality castings, and as such can be
considered approximately equal in their ability to remove
the exogenous silicate inclusions associated with the
pitting defects.
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Figure 11. Average rating of each filter type. |
3.2.2QUANTITATIVE METALLOGRAPHY
The castings from one series underwent quantitative
metallography. This basically involved counting the
number of micro-inclusions present in samples from each
of the castings in the series.
Specimens from the three-inch portion of the casting were
carefully polished to ensure that inclusions were not
torn from the sample. Each specimen was divided up into a
10x10 grid pattern to give 100 fields. Each field
measured 300µm x 350µm. Particles with an area greater
than 160µm2 were eliminated based on the assumption that
these were graphite nodules. It is however inevitable
that some particles included in the count will be
graphite nodules, partially accounting for the relatively
low efficiencies observed.
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Figure 12. Relative filtration efficiencies. |
For the purposes of
presentation, it is assumed that unfiltered castings have
zero filtration efficiency. The number of inclusions
found in the unfiltered casting can therefore be assumed
to be 100%. The relative efficiencies of each filter type
can therefore be calculated. A graph showing this can be
seen in figure 12.
It cannot be claimed that this study represents an
absolute figure for the relative filtration efficiency of
each filter type. The castings are taken from one series
only and, as stated earlier, differences from pour to
pour will always occur. The study does show, however,
that the effects of using filters in general are
considerable in their ability to remove micro and
macro-inclusions. This is shown in both the qualitative
study and the quantitative study.
4FLOW RATE
Consistency of flow is becoming an increasingly important
property. Filters of a particular model should ideally
have a high and consistent flow rate. The filter should
have as little effect on the pour time as possible. Most
ceramic filter manufacturers recommend that the active
face of the filter should have a surface area of between
3 and 5 times that of the system choke, but even if these
recommendations are followed, high variations in the flow
rate can sometimes lead to problems.
Assuming factors such as melt cleanliness, metal
temperature and chemistry are constant the consistency of
flow rate through the filter will depend upon the
consistency of properties such as percentage open area
and porosity.
Studies were undertaken to compare the flow rate
characteristics of the three filter types under review.
The first study (4) was performed on water flow measuring
equipment. The second study (5) used ductile iron.
4.1WATER FLOW RATE
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| Figure 13. Water flow rate of first 25 consecutive filters. |
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Figure 14. Distribution of water flow rates. |
A water flow testing
machine was constructed to compare the flow rate of the
different types of filters. The filters studied were all
50 x 50 mm. The foam filters were 10 ppi, the extruded
were 100 csi and the pressed had a cell diameter of 0.100
inches. These are generally the filter models recommended
for use with ductile iron. The aim was to assess the
consistency of flow from one filter to the next. One
hundred pieces of each filter type were measured to get
an accurate idea of any variation. The filters were the
system choke. Figure 13
shows a graph of the first 25 filters to be measured. As
can be seen there is a high variation in the flow rates
of foam filters, whereas the cellular ceramic filters
show negligible variation. This graph depicts the
variation that would be expected from one filter to
another in normal production. The difference in the
filter types can be seen clearly in the distribution
plots in figure 14.
The distribution curves are normal and this indicates
that the test samples are valid. It can be seen that the
pressed filters and the extruded filters have almost
exactly the same flow rate and consistency.
The reason for the inconsistency in the flow rates of the
foam filters is due to their random nature. There will
always be variations in their porosity and consequently
in the amount of ceramic coating. This variation will
occur within the structure of individual filters and from
filter to filter. Also, due to the random nature of the
foam there will always be "dead spots" were
almost no flow occurs -- much like the water behind rocks
in a fast flowing river. These inconsistencies will
compound to give the variation seen on the graph. If a
filter type has an inconsistent flow rate, it follows
that they will also have an inconsistent capacity.
Filters with areas of fine porosity and low percentage
open area can lead to premature blockage and consequently
short run problems. Conversely, the structure of cellular
filters is highly repeatable. As such, due to the filter
design, there will almost be no inconsistencies in the
flow rate and therefore negligible variation in capacity.
4.2METAL FLOW RATE
Although water flow rate gives a good indication of the
relative consistencies of filter types, it still does not
exactly simulate the flow of iron. When iron is flowing
through a filter, its rate will not be linear. It will
get less over time, due to the non metallic inclusions
progressively blocking more and more of the filter.
Studies performed on the flow rate of iron through
filters (5) mirror the results of the water flow study.
Cellular filters have a significantly higher flow rate
than foam filters. Only one filter of each type was used
for the study. If many filters were tested the trend for
foam filters observed in the water flow study, would
likely be experienced in metal flow also.
5CAPACITY
The capacity of a filter is closely related to flow rate
and filtration efficiency. If a filter has a very high
filtration efficiency, it may be at the expense of flow
rate and capacity. Foundries would ideally like all of
these properties to be high but it is no use having a
filter that has an extremely high efficiency if it is
prone to premature blockage. Conversely, if the capacity
is too high then the filtration efficiency may be
compromised.
Studies, (5), have found that at 2462ºF, (1350ºC), in
ductile iron, extruded filters have a marginally higher
capacity than pressed filters. Both types had a
significantly higher capacity than foam filters. At
2642ºF, (1450ºC), however, the differences between the
filter types are reduced.
In this study only one filter of each type was tested.
Given the inconsistency observed in the water flow rate
study, it could be expected that the foam filters would
also display a similar trend for capacity. Variations in
the capacity of filters is often masked by the use of
large filter areas relative to the system choke.
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Figure 15. Normal distributions of filter length. |
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Figure 16. Normal distributions of filter width. |
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Figure 17. Normal distributions of filter thickness. |
6DIMENSIONAL
CAPABILITY
The dimensional tolerance of filters is becoming
increasingly important. Filters must fit into their
prints first time, every time with minimal danger of
leakage around their edges. This is especially true when
the filters are set automatically. To compare their
dimensional capabilities, one hundred of each filter type
were measured. The pressed filters and the foam filters
were described as 50 mm x 50 mm x 22 mm. The extruded
filters were 55 mm x 55 mm x 13 mm. These were the only
filters that were available for analysis at the time.
Although there are two different sizes of filter, it is
still possible to get a good idea of their capabilities
in terms of dimensional stability. The foam filters were
the "free formed" type with non-machined edges.
The results are presented in figures 15, 16 & 17.
The most dimensionally consistent filter type measured
are the pressed and extruded filters. The foam filters
have almost twice the spread as the pressed and extruded.
This is due mainly to their manufacturing processes.
Pressed filters of a particular reference are
individually made in identical steel dies. This ensures
that each filter will have very close tolerances.
Extruded filters are made by extruding a large log and
then slicing them into individual pieces. Squareness can
be a problem due to log twist before or during slicing.
The foam filters analyzed are made using individually cut
pieces of polyurethane foam. There is therefore a degree
of variation from this cutting process before the ceramic
is coated on the foam. Whilst being coated with ceramic,
the filters will stretch and distort slightly due to the
manufacturing process. The edges of the filters also
contain a significant build up of ceramic material. This
is again due to the forming process. The liquid ceramic
slurry will squeeze out the sides of the foam causing the
build up. Sharp edges can also be formed on the edges of
foam filters. This can cause loose sand to be scraped
away from the mold This could then end up in the casting
cavity.
7COLD STRENGTH
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Figure 18. The relative cold strength of the various filter types. |
The cold strength of
filters is important for handling and shipping purposes.
It is important that pieces of the filters don't loosen
and break off, as these may well end up in the casting.
The filter must also have adequate strength to survive
the closing of the mold.
The cold strength of filters can be measured by
subjecting them to a three point loading test. In this
test, filters are supported on two horizontal pins. A
load is applied from a third pin from above. The load is
increased until the filter breaks and peak load is
recorded. Twenty of each filter type were measured in
this way. The results are reported in the graph in figure 18.
In terms of cold strength, pressed cellular filters are
by far the strongest. This is due to the inherent
advantages of processing ceramics by pressing. The
extruded filters are less than half the strength of the
pressed. The foam filters are less than one third of
their strength. The foam filters are also friable in
nature, (small pieces of the strands tend to break away).
There is a danger that these small pieces may get washed
right through into the casting cavity. This can be
especially dangerous during mold closing especially if
the filters are not dimensionally accurate.
8HOT STRENGTH
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Figure 19. The relative hot strength of the various filter types. |
A filter must obviously
have sufficient strength at molten metal temperatures. To
compare the hot strengths of the filter types in
question, a small furnace was heated to 2732ºF
(1500ºC). Inside the furnace is a refractory tube
measuring 1.60 inches in diameter. The filters are
introduced into the hot furnace through a small opening
at the front, and placed on top of the tube, simulating
the thermal shock experienced in the mold. The furnace is
then allowed to equilibrate for one minute back up to
2732ºF, (1500ºC), after which load is then applied to
the center of the filter with a refractory rod, 0.705
inches in diameter. The load is increased until the
filter breaks. The peak load is then recorded. Ten
samples of each filter type were measured in this way.
The results are illustrated in figure 19.
As can be seen the pressed cellular filters are far
stronger than both the extruded cellular and the foam
filters. The hot strength of pressed cellular filters
measured are on average over twice the strength of both
extruded and foam. This is again due to the inherent
strength advantages of pressed ceramics.
The test described above is only a static test designed
to compare strengths at elevated temperatures. It is
accepted that there are other factors to consider when
iron is poured onto the filters.
9COST
The actual cost of each filter type is impossible to
give. Different manufacturers will have different costs
and each foundry will purchase different volumes.
However, it is generally accepted that at present foam
filters are the most expensive type followed by extruded.
Pressed cellular filters are generally regarded as the
least expensive option of the three in types under
review.
The price difference is due to processing costs. Foam
filters go through a relatively complicated manufacturing
cycle that involves coating a polyurethane precursor with
a ceramic slurry. The filter then usually has to go
through several spraying and drying stages before it is
eventually fired in a kiln. Extruded filters are formed
as a continuous log and individual filters are sliced
from this. Pressed filters are less complicated to
manufacture in that the filter is formed in one pressing
operation after which it is dried and fired.
10GENERAL DISCUSSION
The filtration efficiency study showed that all of the
ceramic filters were effective in their ability to remove
non metallic inclusions and to improve the surface
quality of castings. The main differences between the
filter types were found to be in the areas of strength,
consistency of flow rate, dimensional stability, capacity
and cost.
The water flow study was really aimed at comparing the
consistency of filters rather than attempting to simulate
the flow of iron. The flow rate of a filter will have an
effect on its capacity and also its filtration
efficiency. The higher the flow rate, the higher the
capacity and the lower the filtration efficiency. This
is, of course, also true in the opposite sense.
Therefore, if a filter type has a highly inconsistent
flow rate, it follows that its filtration efficiency and
its capacity will also be variable. The gradual decrease
in the flow rate marks the progressive blockage of the
filter. Kahn et al. (6) studied the fatigue strength of
castings produced from cellular filters and foam filters.
It was found that cellular filters gave more consistently
improved casting quality. Foam filters gave a more
unpredictable casting quality ranging from the best
quality castings to the worst.
All foundries are different and some may not be so
sensitive to some parameters than others, however in
terms of an engineered balance, it is clear that the more
consistent filter solutions are the cellular types. Foam
filters offer good filtration efficiency but they lack
consistency, strength and are generally more expensive.
The extruded filters offer good consistency in terms of
flow rate and dimensional accuracy, but they tend to lack
some strength. The pressed cellular filters give good
filtration efficiency, good consistency in terms of flow
rate and consequently capacity, have good hot and cold
strength, have good dimensional stability and are
generally the least expensive option. As such it is
reasonable to conclude that in ductile iron, pressed
cellular filters offer the best engineered balance of the
performance parameters discussed.
References
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